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Electric potential energy (U)
Energy stored in a system due to the configuration (positions) of electric charges; not a property of an isolated single charge.
Conservative electric force (electrostatics)
Electric force is conservative for time-independent fields, so a potential energy function U can be defined and work depends only on initial and final positions.
Work done by the electric field
Relationship to potential energy change: W_field = −ΔU.
External work (quasistatic move)
If an external agent moves a charge slowly so kinetic energy doesn’t change, the external work equals the potential energy increase: Wext=ΔU.
Point-charge potential energy (two charges)
With U(∞)=0, two point charges have U(r)=krq1q2.
Coulomb constant (k)
k=4πϵ01, the proportionality constant in Coulomb’s-law-based potential and potential energy formulas.
Sign of U for like charges
For q1q2>0, U>0; energy must be added to bring like charges closer together.
Sign of U for opposite charges
For q1q2<0, U<0; energy is released as opposite charges move closer together.
Pairwise sum for potential energy (many charges)
Total potential energy for multiple point charges: U=k∑i<jrijqiqj (sum over distinct pairs to avoid double counting).
Potential-energy-from-potential formula
Equivalent system energy expression: U = (1/2) Σi qi Vi, where Vi is due to all other charges; 1/2 prevents double counting.
Electric potential (V)
Electric potential at a point is potential energy per unit charge: V=qU (a property of the field/source charges, not the test charge).
Volt (V)
Unit of electric potential: 1 V = 1 J/C.
Potential difference (ΔV)
Change in electric potential between two points: ΔV=Vf−Vi.
Potential energy change from potential difference
For a charge q moving between two points: ΔU=qΔV (sign depends on q).
Work–potential relation
Work done by the electric field in moving charge q through ΔV: Wfield=−qΔV.
Reference potential
Potential is defined up to an additive constant; only potential differences are physically measurable (often choose V(∞)=0 when it converges).
Potential of a point charge
With V(∞)=0, a point charge Q produces V(r)=rkQ; sign of V matches sign of Q.
Scalar superposition of potential
Because V is a scalar, potentials add by ordinary addition: Vtotal=k∑iriQi.
Equipotential surface
A set of points with the same V; moving along it gives ΔV=0 ⇒ ΔU=0, so the electric field does no work along the equipotential.
Perpendicularity of E and equipotentials
Electric field lines cross equipotential surfaces at right angles because E points in the direction of greatest decrease of V.
Potential difference from the electric field (line integral)
ΔV=Vb−Va=−∫abE⋅dℓ (path-independent in electrostatics).
Electric field from potential (gradient)
Field is the negative gradient of potential: E=−∇V (in 1D: Ex=−dxdV).
Conductor in electrostatic equilibrium
Inside conducting material, E=0 and the potential is constant throughout the conductor (equal to the surface potential).
Conducting sphere potential
For a conducting sphere (radius R, charge Q, V(∞)=0): V(r)=kQ/r for r≥R and V(r)=kQ/R for r≤R (constant inside).
Potential from charge distributions (integration)
Use dV=krdq and integrate: V=k∫rdq, with dq expressed via λdl, σdA, or ρdτ depending on the distribution.