29.1 Quantization of Energy

29.1 Quantization of Energy

  • They don't have every conceivable value and appear only in certain values.
    • The opposite of continuous is quantized.
  • We can't have a fraction of an atom or part of an electron's charge.
    • Everything is built of multiple substructures.
    • The branch of physics that deals with small objects and quantization is called quantum physics.
    • Similar to classical physics, quantum physics has several subfields, such as mechanics.
    • We begin the development of quantum mechanics in this chapter.
    • We will look at atomic and nuclear physics in later chapters, in which quantum mechanics is important.
  • The classical case is different because the system can only have certain energies and not a continuum.
    • It would be similar to having only certain speeds at which a car can travel.
    • Some forms of energy transfer take place with small amounts of energy.
    • Most of us are familiar with the quantization of matter into small particles called atoms, but we don't know that energy can also be quantized.
    • The quantization of energy was one of the earliest clues about the necessity of quantum mechanics.
  • Classical physics can't describe the shape of the spectrum.
  • Let's consider the emission and absorption of the radiation.
    • The solid's temperature is linked to the EM spectrum.
    • An ideal radiator has an emissivity of 1 at all wavelengths and is jet black.
    • The total intensity of the radiation varies depending on the fourth power of the body's temperature and the peak of the spectrum shifts to shorter wavelengths at higher temperatures.
    • The curve of the spectrum of intensity versus wavelength gave a clue that the atoms in the solid are quantized.
    • At the turn of the century, providing a theoretical explanation for the measured shape of the spectrum was a mystery.
    • The answers to the "ultraviolet catastrophe" led to the development of new technologies such as computers.
    • The way we live was changed by physics.
  • The German physicist Max Planck used the idea that atoms and molecules in a body emit and absorb radiation.
    • To describe the shape of the blackbody spectrum, the energies of the oscillating atoms and molecules had to be quantized.
  • Here is any non negative number.
  • There are some analogies to the quantization of energy phenomena.
    • This is a pendulum that can swing with certain frequencies, but only with certain frequencies.
    • The quantization of energy is similar to a standing wave on a string.
    • It is similar to going up and down a hill using stair steps rather than being able to move up and down a continuous slope.
    • As you move from step to step, your potential energy takes on some values.
  • Planck was able to describe the blackbody spectrum using the quantization of oscillators.
    • This was the first time that quantization of energy on a small scale earned him a prize.
    • The analysis of Planck's theory is based on atoms and molecules.
    • It was such a departure from classical physics that Planck was reluctant to accept his own idea that energy states are not continuous.
    • Einstein's explanation of the photoelectric effect, which took energy quantization a step further, greatly enhanced the general acceptance of Planck's energy quantization.
  • Both quantum mechanics and relativity were developed by Planck.
    • Einstein's special relativity was published in 1905 and the first formula for relativistic momentum was suggested in 1906 by Planck.
  • The first to recognize that energy is sometimes quantized is the German physicist Max Planck.
    • Special relativity and classical physics were made by Planck.
    • The difference between energy levels is only about 0.4 eV for a blackbody emitting an IR Frequency.
    • This 0.4 eV of energy is significant compared with typical atomic energies, which are typically fractions of an electron volt.
    • On a classical scale, the energies are usually on the order of joules.
    • The quantum steps are too small to be noticed.
    • The correspondence principle is used in this example.
    • The results of classical physics are indistinguishable from those of quantum mechanics.
  • Let's look at the emission and absorption of radiation by gases.
    • The Sun is one of the most common examples of a body emitting gases and visible light.
    • Neon signs and candle flames are examples.