2.4 Chemical Formulas

2.4 Chemical Formulas

  • The sample is exposed to a high-energy electron beam that causes the sample's atoms to become charged, typically by losing one or more electrons.
    • The path of a large steel ball bearing rolling past a magnet is affected by the mass and charge of the cations that pass through it.
    • The mass-to-charge ratio is used to calculate the height of each vertical feature.
    • Since its initial use during the development of modern atomic theory,MS has evolved to become a powerful tool for chemical analysis in a wide range of applications.
  • A mass spectrum with peaks showing the different isotopes of Zr is produced by the analysis of zirconium.
  • There is an animation that explains mass spectrometry.
    • You can watch the rudiments of mass spectrometry.
  • The OpenStax book is available for free at http://cnx.org/content/col11760/1.9 compounds.
  • There are symbols for one C atom and four H atoms in the structural formula for methane.
    • The atoms are held together by bonds.
    • We will look at how to predict the arrangement of atoms in a molecule.
    • The lines are an indication of how the atoms are connected in a molecule.
    • A ball-and-stick model shows the geometric arrangement of the atoms with atomic sizes not to scale, and a space-filling model shows the relative sizes of the atoms.
  • A methane molecule can be represented in a number of ways.
    • Black and white spheres represent carbon and hydrogen atoms.
  • Some elements are made up of two or more atoms of the same element.
    • Most samples of the elements hydrogen, oxygen, and nitrogen are composed of molecules that contain two atoms each, and thus have the formula H2, O2, and N2, respectively.
    • Other elements found in diatomic molecule are fluorine, chlorine, bromine, and I2.
    • The most common form of sulfur is composed of eight atoms of sulfur and its formula is S8
  • A molecule of sulfur is composed of eight sulfur atoms.
    • A structural formula, a ball-and-stick model, and a space-filling model can be represented.
    • Yellow spheres represent sulfur atoms.
  • It is important to note that a subscript following a symbol and a number in front of a symbol does not represent the same thing; for example, H2 and 2H are distinctly different species.
    • H2 is a diatomic molecule of hydrogen, consisting of two atoms of the element that are chemically bonding together.
    • The expression 2H indicates that there are two separate hydrogen atoms.
    • The expression 2H2 is a representation of diatomic hydrogen.
  • Two or more elements combine, resulting in the formation of bonds.
    • Hydrogen and oxygen can react to form water, while sodium and chlorine can react to form table salt.
    • An empirical formula of TiO2 can be found in titanium dioxide, which is used in white paint and in the thick, white, blocking type of sunscreen.
    • The element titanium is the component of titanium dioxide, and the element oxygen is the component of titanium dioxide.
  • The titanium and oxygen atoms are different colors.
    • The empirical formula of a substance can be derived from experimental determination of the molecule's atomic mass.
    • For every carbon atom in benzene, there is one hydrogen atom, that's how much carbon there is.
    • The empirical formula is CH.
    • The molecule of benzene contains six carbon atoms and six hydrogen atoms, so the formula for benzene is C6H6 according to an experimental determination of themolecular mass.
  • Benzene has many industrial uses.
    • A benzene molecule can be represented as a structural formula, a ball-and-stick model, and a space-filling model.
  • We can easily determine the empirical formula if we know a compound's formula.
    • acetic acid's component that gives it its sharp taste is C2H4O2.
    • A molecule of acetic acid has two carbon atoms, four hydrogen atoms, and two oxygen atoms.
    • The ratio of atoms is 2:1.
    • The empirical formula is CH2O because of the 1:2:1 whole-number ratio of atoms.
    • A whole-number multiple of an empirical formula is what a molecular formula is.
  • A ball-and-stick model can be represented as a structural formula.
  • 6 carbon atoms, 12 hydrogen atoms, and 6 oxygen atoms are contained in the blood sugar.
  • The formula for the molecule is C6H12O6 because it contains 6 C, 12 H, and 6 O atoms.
    • The empirical formula is CH2O because the simplest whole-number ratio of C to H to O atoms is 1:2.
  • A molecule of metaldehyde has 16 hydrogen atoms, 8 carbon atoms, and 4 oxygen atoms.
  • You can use an online simulation.
  • Chemists make very complicated molecules by chopping up small molecule and "reverse engineering" them.
    • He wonders if we could make a really cool universal chemistry set by what he calls "app-ing" chemistry.
  • The toolkit could be used to create custom-tailored drugs to fight a new superbug or to "print" medicine tailored to your environment and health situation.
    • What Apple did for music, I'd like to do for the discovery and distribution of prescription drugs.
    • The talk "Print Your Own Medicine" was presented at the TED Global 2012 in Edinburgh, Scotland.
  • One of the UK's 10 most inspiring scientists is a chemist.
    • Lee, the youngest chair at the University of Glasgow, has published over 250 papers in top scientific journals and given more than 150 invited talks.
    • His research focuses on chemical systems and their potential to transform technology, but also branches into synthetic biology, artificial life and evolution, and even solar fuels.
  • It is important to be aware that it is possible for the same atoms to be arranged in different ways.
  • If you predicted another compound with the formula C2H4O2 would exist, you showed good chemical insight and were correct.
    • Two C atoms, four H atoms, and two O atoms can be arranged to form a methyl formate, which is used in manufacturing, as an insecticide, and for quick-drying finishes.
    • The arrangement of carbon and oxygen atoms in acetic acid is different than in formate.
  • This small difference in the arrangement of the atoms has a major effect on their respective chemical properties.
    • You wouldn't want to use a solution of methyl formate as a substitute for a solution of acetic acid in salad dressing.
  • The same formula is used for acetic acid and methyl formate, but they have different structures.
  • There are many types of isomers.
    • The compound carvone (found in caraway seeds, spearmint, and mandarin orange peels) consists of two isomers that are mirror images of each other.
    • Carvone smells like spearmint.
  • Molecules of carvone have the same relative orientations of the atoms in space.